tert-Butylsulfinamide CAS:146374-27-8

ʻO ka tert-Butylsulfinamide, i ʻike ʻia hoʻi ʻo N-tert-butanesulfinamide a i ʻole TBSA, he reagent versatile i hoʻohana nui ʻia i nā kaʻina hana synthesis organik like ʻole. Aia kāna noi mua i ka synthesis asymmetric, kahi e lawelawe ai ma ke ʻano he mea kōkua chiral e hoʻoulu i ka stereocontrol i nā ʻano hopena kemika. Ma ka hoʻohana ʻana i nā waiwai steric a me nā uila kū hoʻokahi o ka tert-Butylsulfinamide, hiki i nā chemists ke hoʻokō i nā pae kiʻekiʻe o ka enantioselectivity, e hoʻomaʻamaʻa ana i ka hana ʻana o nā hui optically pure koʻikoʻi i nā lāʻau lapaʻau, nā agrochemicals, a me nā kemika maikaʻi. ʻO kekahi o nā hoʻohana koʻikoʻi o ka tert-Butylsulfinamide ʻo ia ka hoʻohui enantioselective o nā reagents organometallic i nā imines, e hiki ai ke kūkulu ʻia nā amines chiral, kahi i ʻike nui ʻia i nā molekala biologically active. Eia kekahi, ua loaʻa ka tert-Butylsulfinamide i ka noi i nā hopena hōʻemi asymmetric, e hāʻawi ana i kahi ala e hana ai i nā amines chiral a me nā alcohols me ka stereoselectivity kiʻekiʻe. Eia kekahi, he kuleana koʻikoʻi ko tert-Butylsulfinamide i ka synthesis o chiral sulfinamides, e lawelawe ana ma ke ʻano he mau waena waiwai i nā hoʻololi kemika like ʻole. ʻO kona hiki ke hāʻawi i ka mana stereochemical ua alakaʻi i kona hoʻohana nui ʻia ʻana i ka hoʻomākaukau ʻana i nā mea lāʻau lapaʻau, nā huahana kūlohelohe, a me nā mea holomua. Eia kekahi, ʻo ka hoʻomohala ʻana i nā ʻano hana synthetic hou e pili ana i ka tert-Butylsulfinamide e hoʻomau nei i ka hoʻonui ʻana i kona pono ma ke aupuni o ka kemika organik. Mai nā hoʻololi asymmetric catalytic a hiki i ka synthesis o nā poloka hale paʻakikī, ke noho nei kēia reagent i kihi i ka ʻimi ʻana i ka synthesis kemika kūpono a koho. I ka hōʻuluʻulu manaʻo, kū ʻo tert-Butylsulfinamide ma ke ʻano he mea hana pono ʻole no nā chemists e ʻimi nei e komo i nā hui enantiopure me ka stereochemistry i hana ʻia. ʻO kona hopena e pālahalaha ana ma nā kahua o ka ʻike lāʻau lapaʻau, ka synthesis kemika, a me ka ʻepekema mea, e hōʻike ana i kona koʻikoʻi ma ke ʻano he reagent versatile a ikaika i ka kemika organik hou.